195Pt NMR isotopologue and isotopomer distributions of [PtCln(H2O)6 - N]4 - n (n = 6,5,4) species as a fingerprint for unambiguous assignment of isotopic stereoisomers

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dc.contributor.authorGerber W.J.
dc.contributor.authorMurray P.
dc.contributor.authorKoch K.R.
dc.date.accessioned2011-05-15T15:59:06Z
dc.date.available2011-05-15T15:59:06Z
dc.date.issued2008
dc.description.abstractA detailed analysis of the 35Cl/37Cl isotope shifts induced in the 128.8 MHz 195Pt NMR resonances of [PtCl n(H2O)6 - n]4 - n complexes (n = 6,5,4) in acidic solution at 293 K, shows that the unique isotopologue and isotopomer distribution displayed by the resolved 195Pt resonances, serve as a fingerprint for the unambiguous identification and assignment of the isotopic stereoisomers of [PtCl5(H2O)]- and cis/trans-[PtCl4(H2O)2]. © 2008 The Royal Society of Chemistry.
dc.description.versionArticle
dc.identifier.citationDalton Transactions
dc.identifier.citation31
dc.identifier.issn14779226
dc.identifier.other10.1039/b807831a
dc.identifier.urihttp://hdl.handle.net/10019.1/11001
dc.title195Pt NMR isotopologue and isotopomer distributions of [PtCln(H2O)6 - N]4 - n (n = 6,5,4) species as a fingerprint for unambiguous assignment of isotopic stereoisomers
dc.typeArticle
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